April 20, 2024

Scientists Infuse Bacteria With Silver Nanoparticles To Improve Power Efficiency in Fuel Cells

Artists principle of a microbial fuel cell with performances boosted by silver nanoparticles. Credit: Image produced by AKang, Sphere Studio. Copyright: Yu Huang and Xiangfeng Duan
A UCLA-led team of engineers and chemists has actually taken a major advance in the development of microbial fuel cells– an innovation that uses natural bacteria to draw out electrons from natural matter in wastewater to produce electrical currents. A research study detailing the advancement was recently published in Science.
” Living energy-recovery systems using germs found in wastewater provide a one-two punch for environmental sustainability efforts,” said co-corresponding author Yu Huang, a professor and chair of the Materials Science and Engineering Department at the UCLA Samueli School of Engineering. “The natural populations of bacteria can assist decontaminate groundwater by breaking down damaging chemical compounds. Now, our research study likewise shows a practical way to harness renewable resource from this process.”
The group focused on the bacteria genus Shewanella, which have been widely studied for their energy-generation abilities. They can thrive and grow in all types of environments– including soil, seawater and wastewater– despite oxygen levels.

Shewanella species naturally break down natural waste matter into smaller sized particles, with electrons being a byproduct of the metabolic procedure. When the germs grow as movies on electrodes, a few of the electrons can be recorded, forming a microbial fuel cell that produces electrical power.
Microbial fuel cells powered by Shewanella oneidensis have formerly not caught enough currents from the germs to make the innovation practical for commercial usage. Few electrons could move rapidly enough to escape the bacterias membranes and enter the electrodes to provide enough electrical currents and power.
To resolve this issue, the scientists included nanoparticles of silver to electrodes that are composed of a type of graphene oxide. The nanoparticles release silver ions, which germs minimize to silver nanoparticles using electrons generated from their metabolic process and after that incorporate into their cells. Once inside the germs, the silver particles act as microscopic transmission wires, capturing more electrons produced by the germs.
” Adding the silver nanoparticles into the germs is like producing a devoted express lane for electrons, which enabled us to draw out more electrons and at faster speeds,” said Xiangfeng Duan, the research studys other corresponding author and a teacher of chemistry and biochemistry at UCLA.
With considerably enhanced electron transportation effectiveness, the resulting silver-infused Shewanella film outputs more than 80% of the metabolic electrons to external circuit, producing a power of 0.66 milliwatts per square centimeter– more than double the previous best for microbial-based fuel cells.
With the increased enhanced and present effectiveness, the study, which was supported by the Office of Naval Research, showed that fuel cells powered by silver-Shewanella hybrid germs might pave the way for adequate power output in practical settings.
Reference: “Silver nanoparticles improve charge-extraction performance in Shewanella microbial fuel cells” by Bocheng Cao, Zipeng Zhao, Lele Peng, Hui-Ying Shiu, Mengning Ding, Frank Song, Xun Guan, Calvin K. Lee, Jin Huang, Dan Zhu, Xiaoyang Fu, Gerard C. L. Wong, Chong Liu, Kenneth Nealson, Paul S. Weiss, Xiangfeng Duan and Yu Huang, 17 September 2021, Science.DOI: 10.1126/ science.abf3427.
Bocheng Cao, a UCLA doctoral student recommended by both Huang and Duan, is the first author of the paper. Other UCLA senior authors are Gerard Wong, a teacher of bioengineering; Paul Weiss, a UC Presidential Chair and prominent professor of chemistry and biochemistry, bioengineering, and products science and engineering; and Chong Liu, an assistant teacher of chemistry and biochemistry. Kenneth Nealson, a teacher emeritus of earth sciences at USC, is likewise a senior author.
Duan, Huang and Weiss are all members of the California NanoSystems Institute at UCLA.

” Living energy-recovery systems utilizing bacteria discovered in wastewater offer a one-two punch for ecological sustainability efforts.”– Yu Huang

Artists principle of a microbial fuel cell with performances improved by silver nanoparticles.” Living energy-recovery systems making use of germs discovered in wastewater offer a one-two punch for environmental sustainability efforts,” said co-corresponding author Yu Huang, a professor and chair of the Materials Science and Engineering Department at the UCLA Samueli School of Engineering. “The natural populations of germs can assist decontaminate groundwater by breaking down harmful chemical compounds. The nanoparticles release silver ions, which bacteria reduce to silver nanoparticles utilizing electrons created from their metabolic procedure and then include into their cells. As soon as inside the germs, the silver particles act as tiny transmission wires, recording more electrons produced by the germs.