March 28, 2024

Extreme Geophysics: Quantum Phase Transition Detected on a Global Scale Deep Inside the Earth

By Columbia University School of Engineering and Applied Science
October 17, 2021

Illustration to accompany Nature Communications paper, “Seismological expression of the iron spin crossover in ferropericlase in the Earths lower mantle.” Credit: Nicoletta Barolini/Columbia Engineering
Multidisciplinary team of products physicists and geophysicists combine theoretical predictions, simulations, and seismic tomography to discover spin shift in the Earths mantle.
Researchers only have seismic tomographic images of this area and, to translate them, they need to compute seismic (acoustic) velocities in minerals at high pressures and temperature levels. When a phase transition happens in a mineral, such as a crystal structure change under pressure, researchers observe a velocity change, normally a sharp seismic speed discontinuity.
In 2003, scientists observed in a lab an unique type of stage change in minerals– a spin change in iron in ferropericlase, the second most abundant element of the Earths lower mantle. A spin modification, or spin crossover, can happen in minerals like ferropericlase under an external stimulus, such as pressure or temperature.

Cold, subducting oceanic plates are seen as quick speed regions in (a) and (b), and warm rising mantle rock is viewed as sluggish velocity regions in (c). Plates and plumes produce a coherent tomographic signal in S-wave designs, but the signal partially vanishes in P-wave models. Credit: Columbia Engineering
In 2006, Columbia Engineering Professor Renata Wentzcovitch published her very first paper on ferropericlase, offering a theory for the spin crossover in this mineral. Her theory suggested it took place throughout a thousand kilometers in the lower mantle. Ever since, Wentzcovitch, who is a teacher in the applied physics and used mathematics department, earth and environmental sciences, and Lamont-Doherty Earth Observatory at Columbia University, has actually released 13 papers with her group on this topic, examining velocities in every possible circumstance of the spin crossover in ferropericlase and bridgmanite, and forecasting homes of these minerals throughout this crossover. In 2014, Wenzcovitch, whose research concentrates on computational quantum mechanical research studies of materials at severe conditions, in particular planetary products anticipated how this spin modification phenomenon could be identified in seismic tomographic images, however seismologists still might not see it.
Dealing with a multidisciplinary group from Columbia Engineering, the University of Oslo, the Tokyo Institute of Technology, and Intel Co., Wenzcovitchs newest paper information how they have actually now identified the ferropericlase spin crossover signal, a quantum phase transition deep within the Earths lower mantle. This was attained by looking at specific regions in the Earths mantle where ferropericlase is expected to be plentiful. The study was released on October 8, 2021, in Nature Communications.
” This amazing finding, which verifies my earlier predictions, shows the importance of products physicists and geophysicists working together to find out more about whats going on deep within the Earth,” stated Wentzcovitch.
Spin shift is typically utilized in products like those utilized for magnetic recording. You can change the layers magnetic residential or commercial properties and improve the medium recording residential or commercial properties if you stretch or compress simply a few nanometer-thick layers of a magnetic product. Wentzcovitchs new research study shows that the very same phenomenon takes place across countless kilometers in the Earths interior, taking this from the nano- to the macro-scale.
” Moreover, geodynamic simulations have actually revealed that the spin crossover stimulates convection in the Earths mantle and tectonic plate motion. We think that this quantum phenomenon also increases the frequency of tectonic occasions such as earthquakes and volcanic eruptions,” Wentzcovitch notes.
There are still numerous areas of the mantle scientists do not understand and spin state change is crucial to understanding speeds, phase stabilities, and so on. Wentzcovitch is continuing to interpret seismic tomographic maps utilizing seismic speeds forecasted by ab initio computations based on density functional theory. She is also developing and using more accurate products simulation techniques to anticipating seismic speeds and transport homes, especially in areas rich in iron, molten, or at temperatures near melting.
” Whats especially exciting is that our products simulation methods apply to strongly correlated products– multiferroic, ferroelectrics, and products at heats in basic,” Wentzcovitch says. “Well have the ability to improve our analyses of 3D tomographic images of the Earth and find out more about how the squashing pressures of the Earths interior are indirectly affecting our lives above, on the Earths surface.”
Referral: “Seismological expression of the iron spin crossover in ferropericlase in the Earths lower mantle” by Grace E. Shephard, Christine Houser, John W. Hernlund, Juan J. Valencia-Cardona, Reidar G. Trønnes and Renata M. Wentzcovitch, 8 October 2021, Nature Communications.DOI: 10.1038/ s41467-021-26115-z.

In 2003, scientists observed in a laboratory a novel type of phase modification in minerals– a spin change in iron in ferropericlase, the 2nd most plentiful component of the Earths lower mantle. A spin change, or spin crossover, can take place in minerals like ferropericlase under an external stimulus, such as pressure or temperature. Because then, Wentzcovitch, who is a professor in the used physics and applied mathematics department, earth and ecological sciences, and Lamont-Doherty Earth Observatory at Columbia University, has released 13 papers with her group on this subject, investigating speeds in every possible circumstance of the spin crossover in ferropericlase and bridgmanite, and anticipating homes of these minerals throughout this crossover. Working with a multidisciplinary group from Columbia Engineering, the University of Oslo, the Tokyo Institute of Technology, and Intel Co., Wenzcovitchs latest paper details how they have now identified the ferropericlase spin crossover signal, a quantum phase shift deep within the Earths lower mantle. Wentzcovitchs new research study reveals that the exact same phenomenon takes place throughout thousands of kilometers in the Earths interior, taking this from the nano- to the macro-scale.