November 22, 2024

Nanodiamonds Are Key to Efficient Hydrogen Purification – And a Zero-Carbon Future

This image provides an abstract graph of graphene oxide sheets (black layers) embedded with nanodiamonds (bright white points). The nanodiamonds put in long variety electrostatic forces (nebulous white circles) which support the sheets even in humid conditions developing a promising membrane material for hydrogen purification. Credit: Yasuhiro Chida (Brocken 5) and Toru Tsuji (Photograph).
Nanodiamonds may be tiny, however they can aid with one of the greatest issues facing mankind today: Climate modification.
Hydrogen, a clean-burning fuel, leaves nothing but water when taken in. Lots of nations view hydrogen as a way to a zero-carbon future, however changing to a hydrogen economy needs its production to be far more budget friendly than it is now.
In a study released in Nature Energy just recently, researchers led by Kyoto Universitys Institute for Integrated Cell-Material Sciences (iCeMS) explain how nanodiamond-reinforced composite membranes can cleanse hydrogen from its humid mixes, making the hydrogen generation processes significantly more cost-effective and effective.

” There are several scalable methodologies to produce hydrogen, but hydrogen typically comes as damp mixtures and their purification is a challenge,” says Professor Easan Sivaniah, who led the iCeMS team. “Membrane technology permits economical and energy-efficient separation procedures. We need to have the best membrane materials to make it work,” Sivaniah added.
Graphene oxide (GO), a water-soluble derivative of graphite, can be put together to form a membrane that can be utilized for hydrogen filtration. Hydrogen gas easily passes through these filters, while larger particles get stuck.
Hydrogen is usually separated from CO2 or O2 in extremely damp conditions. GO sheets are negatively charged, which causes them to drive away each other. When exposed to humidity, the adversely charged sheets repel each other a lot more, enabling water particles to accumulate in the areas in between the GO sheets, which ultimately liquifies the membrane.
Dr. Behnam Ghalei, who co-supervised the research, explained that adding nanodiamonds to the GO sheets solves the humidity-induced disintegration problem. “Positively charged nanodiamonds can counteract the membranes unfavorable repulsions, making the GO sheets more water-resistant and compact.”.
The Institute for Quantum Life Science (QST) assisted with products development. ShanghaiTech University (China) and National Central University (Taiwan) were involved in state-of-the-art materials characterizations.
” In our collaboration with Dr. Ryuji Igarashi of QST, we had the ability to gain access to nanodiamonds with well-defined sizes and functionality, without which the research study would not have been possible,” says Sivaniah. “Importantly, Igarashis group has a trademarked innovation to scale up nanodiamonds production at a sensible cost in the future.”.
Sivaniah states that nanodiamonds have potential usages beyond hydrogen production. Humidity control is likewise important in a variety of other fields, including pharmaceuticals, semiconductors, and lithium-ion battery production. Membrane technology could also change air conditioning by effectively eliminating humidity. Air conditioners are among the most ineffective ways to cool, as a substantial amount of the electricity utilized to power them is utilized to remove humidity, creating more CO2 emissions and developing a vicious spiral for international warming.
The Japanese government is deeply committed to a zero-carbon future. It has actually established a US$ 20 billion Green Innovation Fund to support joint partnerships between significant market gamers and entrepreneurial endeavors that bring brand-new technologies to the marketplace.
Recommendation: “Overcoming humidity-induced swelling of graphene oxide-based hydrogen membranes using charge-compensating nanodiamonds” by Guoji Huang, Behnam Ghalei, Ali Pournaghshband Isfahani, H. Enis Karahan, Daiki Terada, Detao Qin, Conger Li, Masahiko Tsujimoto, Daisuke Yamaguchi, Kunihisa Sugimoto, Ryuji Igarashi, Bor Kae Chang, Tao Li, Masahiro Shirakawa and Easan Sivaniah, 16 December 2021, Nature Energy.DOI: 10.1038/ s41560-021-00946-y.
iCeMS at Kyoto University is one of the leading institutes in Japan for innovative methods in engaging science to assist society. Sivaniah is the creator of OOYOO, a start-up which aims to be crucial in advertising membrane technology for a zero-carbon future.

The nanodiamonds exert long variety electrostatic forces (nebulous white circles) which stabilize the sheets even in humid conditions creating a promising membrane material for hydrogen purification.” There are several scalable methodologies to produce hydrogen, however hydrogen typically comes as damp mixes and their filtration is a challenge,” states Professor Easan Sivaniah, who led the iCeMS group. Hydrogen is typically separated from CO2 or O2 in really damp conditions. When exposed to humidity, the negatively charged sheets ward off each other even more, allowing water molecules to accumulate in the areas in between the GO sheets, which eventually liquifies the membrane.
Sivaniah states that nanodiamonds have potential uses beyond hydrogen production.