November 22, 2024

The Dendrite Dilemma: New Research Could Overcome Limits of Lithium Batteries

A new technique established by TIFRH researchers significantly improves lithium metal battery security and durability by modifying the separator membrane to reduce dendrite development. This scalable, cost-efficient method deals with difficulties at high present densities, guaranteeing further advancements in battery technology.Lithium metal batteries (LMBs) can supply nearly 10 times greater energy density compared to the present Lithium-ion batteries (LIBs) and hence are determined as one of the prospective future storage systems. Nevertheless, LMBs position specific safety concerns and can not be used for fast-charging applications. Uncontrolled dendrite development, causing excessive heating and battery brief circuit is one of the crucial obstacles of its advancement.Researchers have actually previously tried to attend to the safety concerns in LMBs however with techniques that were money/time and laboursome extensive. T. N. Narayanans lab at the Tata Institute of Fundamental Research, Hyderabad (TIFRH) reports a simple, scalable, cost-efficient method to put together a much safer and more durable lithium metal battery.Preeti Yadav (author) holding a radiant red LED (3V) powered by the modified separator-based lithium metal battery. Credit: Dr. Pallavi Thakur and Prof. T. N. NarayananA permeable separator membrane lies in between the electrodes in a battery, keeping them apart, and is crucial to prevent a short circuit. When a battery is utilized for a long time, tree-like structures or whiskers called dendrites start to form on one of the electrodes. They might in some sense end up being a physical bridge in between the two electrodes triggering a brief circuit if these dendrites grow uncontrollably. Preeti Yadav and Pallavi Thakur, graduate students and lead authors of the research study, used a commonly readily available graphite acquired powder to customize the separator membrane utilized in a normal battery. This adjustment reduces dendrite development and improves the longevity of the battery to a big degree. The scientists propose that this approach of separator modification holds enormous capacity to be scaled up for industrial usage.However, at a really high present density of 10 mA cm-2, the battery seems to be weakening slowly. This might be due to the fact that of the electroplating of lithium on the carbon (a part of the deposited graphite derivative layer). The researchers intend to investigate these difficulties even more and comprehend the function of user interfaces in improving the efficiency of a battery from an essential standpoint.Reference: “High Rate, Dendrite Free Lithium Metal Batteries of Extended Cyclability via a Scalable Separator Modification Approach” by Preeti Yadav, Pallavi Thakur, Dipak Maity and Tharangattu N. Narayanan, 12 December 2023, Small.DOI: 10.1002/ smll.202308344 The study was funded by the Tata Institute of Fundamental Research Hyderabad.