May 4, 2024

We need to make more sustainable fertilizers. This is how we could do it

” The significance of the chemical market ( responsible for ~ 2 Gt CO2 emissions, or ~ 5% of worldwide emissions in 2020) and the problem in attaining net-zero emissions, was a significant motivation for us to start dealing with it. I think this will be a major research avenue for the next 10-15 years,” the researcher adds.

They assist feed the world, and about half of todays population is completely reliant on them, but synthetic fertilizers also account for an important part of our greenhouse gas emissions. While phosphorus and potassium can be mined as salts, nitrogen fertilizer is currently produced through a process that is extremely energy- extensive and presently needs large quantities of natural gas or coal.

The good news is that while the route to green fertilizers is complex and needs numerous measures, we can do it with todays technology– future tech could of course assistance, however we dont require to count on it.

Having said that, the advancement of brand-new procedures and the release and optimization of existing (currently readily available) procedures for the production of net-zero fertilizers will keep us busy for numerous years to come.”

The research study was released in the journal Environmental Research Letters.

The issue is that electrifying fertilizer production (using water electrolysis, which depends on electrical power) requires 25 times as much energy as todays production using gas. Even for countries with plentiful water, wind, and solar energy, it may be hard to spare the needed energy, and might create competition with other sectors that need sustainable energy.

” At the moment, we are not there yet to implement green nitrogen fertilizers. I believe that the energy and food crises, for this reason the requirement to phase out natural gas, substantially catalyzed the shift to tidy innovation solutions. Having said that, the advancement of new procedures and the implementation and optimization of existing (already readily available) procedures for the production of net-zero fertilizers will keep us busy for numerous years to come.”

” Such routes can be implemented today, as innovations are offered. While expenses can be greater depending on the cost of natural gas, our company believe that innovation routes based upon biomass and electrification ( through the production of green hydrogen), can lower the production costs of ammonia in a world of high natural gas prices. Obviously, this comes together with a reduced reliance on gas, which enables accomplishing net-zero emissions,” the researcher adds in an email.

” The analysis recommends that the offered net-zero routes (CCS, electrification, biomass) will need to be integrated based on readily available resources: CCS when underground storage capacity and CO2 infrastructures are available; electrification when big renewable generation capacity are available; biomass when land and water are available. We have not determined the ideal mix of net-zero routes based on the specific area. That would be a good follow-up however needs picking the objective and restraints that specify the “ideal” mix: these might be cost, carbon emissions, water usage, and so forth.”

Our agriculture depends upon fertilizers. Image credits: James Baltz.

Gabrielli is taking a look at ways through which the chemical industry can achieve net-zero CO2 emissions, but he also concurs its an uphill struggle.

But Gabrielli also offers us a reality check. While net absolutely no fertilizers may be technically feasible today, they will require trade-offs in terms of other resources like land and water, and even if our society truly focuses on them, this will be a massive challenge that will take several years to bear fruit.

The matter is even more pressing considering that price quotes show that by 2050, we will require to double food production to fulfill growing demand– and nitrogen fertilizers are important to doing so. Furthermore, Russias invasion of Ukraine revealed simply how frail much of our food systems truly are and how easy it is to unbalance it.

Fertilizers are a bigger environmental issue than you think. They assist feed the world, and about half of todays population is entirely dependent on them, but artificial fertilizers likewise represent a fundamental part of our greenhouse gas emissions. While phosphorus and potassium can be mined as salts, nitrogen fertilizer is presently produced through a process that is extremely energy- extensive and currently needs big quantities of natural gas or coal.

As more countries focus on renewable targets, net-zero fertilizers that dont rely on fossil fuels become more and more essential. Eventually, if we really desire to reach net no, theres most likely no way to do this without net zero fertilizers.

Utilizing more sustainable energy in the process, rather of natural gas (and especially coal) would be a simple method to offset some of the emissions associated with fertilizer. It depends on having adequate sustainable energy for other uses– so much so that you have some energy to spare for fertilizers.

The third path would be manufacturing hydrogen from biomass. Biomass needs a great deal of arable land and water, often contending with farming, however it makes sense if the feedstock is waste biomass (crop residues).

” The chemical market consists of numerous items that contain carbon (such as plastics, garments, methanol), and is therefore virtually difficult to decarbonize. This is why the chemical market is one of the so-called hard-to-abate sectors ( like steel, cement, or aviation),” Gabrielli tells ZME Science.

None of these paths is best, Gabrielli highlights. If we are to truly make the fertilizer industry more sustainable, we need to combine all of them based upon local resources and abilities.

Utilizing more eco-friendly energy in the procedure, rather of natural gas (and particularly coal) would be a basic method to balance out some of the emissions associated with fertilizer. It depends on having enough eco-friendly energy for other usages– so much so that you have some energy to spare for fertilizers.

This is why this essential part of agriculture is often thought to be difficult to decarbonize. However Paolo Gabrielli from ETH Zurich believes in a different way.

Together with associate Lorenzo Rosa, Principal Investigator at Carnegie Institution for Science in Stanford, United States, he set out to explore methods which net-zero fertilizers might be produced.

The second path focuses on saving the carbon produced through conventional, nonrenewable fuel source methods. Essentially, the nitrogen-producing plants would be fitted with carbon capture and storage (CCS), infrastructure for catching and storing the CO2. This would likewise need a great deal of new infrastructure and would not decrease our dependence on fossil fuels, however would decrease a few of the emissions.

Image credits: Etienne Girardet.

Fertilizers increase crop yields, so its not foreseeable that we would simply offer up on them anytime soon– theyre essential for food security. As Gabrielli reported in a brand-new study, producing nitrogen more sustainably would not only help against environment change, however also increase countries food security. How do you do it?